ArNMeCH(SiMe3)2: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes

Shunfa Liu; Yufan Yang; Lu Gao; Zhenlei Song

doi:10.1039/D0CC02277B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

ArNMeCH(SiMe₃)₂: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes†

Shunfa Liu,^a Yufan Yang,^a Lu Gao*^a and Zhenlei Song

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu, China
E-mail: lugao@scu.edu.cn, zhenleisong@scu.edu.cn

Abstract

ArNMeCH(SiMe₃)₂ has been developed as a useful precursor of a formal α-aminoalkyl diradical in Ru(bpy)₃Cl₂-catalzyed addition with alkenes under visible-light-mediated photoredox conditions. This approach leads to homo-diaddition with two identical alkenes in one-pot, or hetero-diaddition with two different alkenes via a sequential operation.

Download options Please wait...

Supplementary files

Supplementary information PDF (7463K)

Article information

DOI: https://doi.org/10.1039/D0CC02277B
Article type: Communication
Submitted: 28 Mar 2020
Accepted: 22 May 2020
First published: 25 May 2020

Download Citation

Chem. Commun., 2020,56, 7487-7490

Permissions

Request permissions

ArNMeCH(SiMe₃)₂: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes

S. Liu, Y. Yang, L. Gao and Z. Song, Chem. Commun., 2020, 56, 7487 DOI: 10.1039/D0CC02277B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications