An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.
D. Shimoyama, R. Sekiya and T. Haino, Chem. Commun., 2020, 56, 3733 DOI: 10.1039/D0CC00933D
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