Issue 34, 2019
From the journal:

Organic & Biomolecular Chemistry

First α-deuterium nitroxides; synthesis and EPR study†

Hila Toledo,ab   Boris Tumanskii, ORCID logo *b   Denis Sh. Sabirov, ORCID logo c   Alexander Kaushansky,b   Natalia Fridmanb  and  Alex M. Szpilman ORCID logo *a  

* Corresponding authors

a Department of Chemical Sciences, Ariel University, Israel
E-mail: amszpilman@gmail.com

b Schulich Faculty of Chemistry, Technion – Israel Institute of Technology, Israel

c Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract

Herein is reported the first preparation of stable α-deuterium nitroxides of the IAPNO family. The confirmation and characteristics of the α-deuterium nitroxides and their α-hydrogen analogues are compared and analyzed. Such α-deuterium nitroxides may find use in biology, medicine and physical chemistry.

Graphical abstract: First α-deuterium nitroxides; synthesis and EPR study

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Article information

DOI
https://doi.org/10.1039/C9OB01127G
Article type
Paper
Submitted
14 May 2019
Accepted
06 Aug 2019
First published
07 Aug 2019

Org. Biomol. Chem., 2019,17, 7900-7906

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First α-deuterium nitroxides; synthesis and EPR study

H. Toledo, B. Tumanskii, D. Sh. Sabirov, A. Kaushansky, N. Fridman and A. M. Szpilman, Org. Biomol. Chem., 2019, 17, 7900 DOI: 10.1039/C9OB01127G

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