Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x(μ4-O)4(O2CPh)18] cluster†
Jan
Nawrocki, 
a
Daniel
Prochowicz,
a
Iwona
Justyniak,
a
Jan
van Leusen,
b
Arkadiusz
Kornowicz,
a
Paul
Kögerler
b
and
Janusz
Lewiński
*ac
a
Daniel
Prochowicz,
a
Iwona
Justyniak,
a
Jan
van Leusen,
b
Arkadiusz
Kornowicz,
a
Paul
Kögerler
b
and
Janusz
Lewiński
*ac
Abstract
The charge-neutral bimetallic Zn(II)/Co(II) tridecanuclear oxocarboxylate cluster [ZnxCo13–x(μ4-O)4(O2CPh)18] (x ≈ 5.6) was synthesized under anaerobic conditions by the controlled hydrolysis of an alkylzinc carboxylate [EtZn(O2CPh)] in the presence of cobalt(II) benzoate Co(O2CPh)2. The composition and molecular structure of the resulting aggregates were solved by a combination of elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction.
![Graphical abstract: Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x(μ4-O)4(O2CPh)18] cluster](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C9DT02791B&imageInfo.ImageIdentifier.Year=2019)
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