A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO2 to formate†
Eric R.
Wolfson 
a
and
Psaras L.
McGrier
*a
a
and
Psaras L.
McGrier
*a
Abstract
A ruthenium porphyrin-based porous organic polymer (POP) was synthesized, characterized, and used to reduce CO2 to a formate salt. We demonstrate that Ru-BBT-POP can be utilized to reduce CO2 to a silyl formate and then converted to potassium formate with a respectable turnover number and frequency.
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