Issue 19, 2019
From the journal:

Chemical Communications

Homochiral iron(ii)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel†

Jia-Ge Jia,a   Jian-Shen Feng,a   Xin-Da Huang,a   Song-Song Bao*a  and  Li-Min Zheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China
E-mail: lmzheng@nju.edu.cn, baososo@nju.edu.cn

Abstract

Homochiral iron(II)-based nanotubular metal phosphonates (R)- and (S)-[Fe(pemp)(H2O)2] [pemp2− = (R)- or (S)-(1-phenylethylamino)methylphosphonate] are reported showing metamagnetism at low temperature. The dehydrated product features coordinatively unsaturated and redox-active metal ion sites that enable it to strongly bind nitric oxide at room temperature.

Graphical abstract: Homochiral iron(ii)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel

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Article information

DOI
https://doi.org/10.1039/C9CC00506D
Article type
Communication
Submitted
20 Jan 2019
Accepted
04 Feb 2019
First published
08 Feb 2019

Chem. Commun., 2019,55, 2825-2828

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Homochiral iron(II)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel

J. Jia, J. Feng, X. Huang, S. Bao and L. Zheng, Chem. Commun., 2019, 55, 2825 DOI: 10.1039/C9CC00506D

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