A new semiconducting 1D Cu(I)–Cu(II) mixed-valence coordination polymer with Cu(II) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu(I)–Br cluster unit

K. Himoto; S. Suzuki; T. Okubo; M. Maekawa; T. Kuroda-Sowa

doi:10.1039/C7NJ04763K

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A new semiconducting 1D Cu(i)–Cu(ii) mixed-valence coordination polymer with Cu(ii) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu(i)–Br cluster unit†

K. Himoto,^a S. Suzuki,^a T. Okubo,

*^a M. Maekawa

^b and T. Kuroda-Sowa^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka, Japan
E-mail: okubo_t@chem.kindai.ac.jp

^b Research Institute for Science and Technology, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka, Japan

Abstract

A novel mixed-valence coordination polymer [Cu^I₄Cu^IIBr₄(dmpip-dtc)₂(CH₃CN)]_n (dmpip-dtc = dimethylpiperidine–dithiocarbamate) with an infinite one-dimensional structure was synthesized and structurally characterized using X-ray diffraction. The electronic properties of the coordination polymer were investigated by UV-vis-NIR spectroscopy. Impedance measurement results demonstrated that this complex has a narrow bandgap, inducing semiconducting behavior.

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Article information

DOI: https://doi.org/10.1039/C7NJ04763K
Article type: Letter
Submitted: 04 Dec 2017
Accepted: 15 Feb 2018
First published: 16 Feb 2018

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New J. Chem., 2018,42, 3995-3998

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A new semiconducting 1D Cu(I)–Cu(II) mixed-valence coordination polymer with Cu(II) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu(I)–Br cluster unit

K. Himoto, S. Suzuki, T. Okubo, M. Maekawa and T. Kuroda-Sowa, New J. Chem., 2018, 42, 3995 DOI: 10.1039/C7NJ04763K

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New Journal of Chemistry

A new semiconducting 1D Cu(i)–Cu(ii) mixed-valence coordination polymer with Cu(ii) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu(i)–Br cluster unit†

Abstract

Supplementary files

Article information

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A new semiconducting 1D Cu(I)–Cu(II) mixed-valence coordination polymer with Cu(II) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu(I)–Br cluster unit

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