Azine based smart probe for optical recognition and enrichment of Mo(vi )

Abstract

Single crystal X-ray structure-characterized azine derivative (L) was explored for the selective detection of molybdenum (Mo(VI)) cations through green fluorescence emission. The Mo(VI) cation assisted inhibition of photo-induced electron transfer (PET) resulted in a 37-fold fluorescence enhancement via chelation enhanced fluorescence (CHEF) that allows detection of Mo(VI) with concentration as low as 2 × 10⁻⁹ M. The chelation of Mo(VI) cations by L has been confirmed by the single crystal X-ray structure of the resulting complex. The binding constant of L for Mo(VI) is fairly high (1.33 × 10⁶ M⁻¹). Moreover, L is very efficient for enrichment of Mo(VI) from aqueous solution. Density functional theoretical (DFT) studies substantiate the experimental results.