Issue 21, 2018
From the journal:

Dalton Transactions

Self-assembly of a mixed-valence FeII–FeIII tetranuclear star†

Darunee Sertphon, ORCID logo ‡a   Phimphaka Harding, ORCID logo a   Keith S. Murray, ORCID logo b   Boujemaa Moubaraki,b   Nicholas F. Chilton, ORCID logo c   Stephen Hill,de   Jonathan Marbey,de   Harry Adams,f   Casey G. Davies,g   Guy N. L. Jameson ORCID logo gh  and  David J. Harding ORCID logo *a  

* Corresponding authors

a Functional Materials and Nanotechnology Centre of Excellence, Walailak University, Thasala, Nakhon Si Thammarat, Thailand
E-mail: hdavid@mail.wu.ac.th

b School of Chemistry, Monash University, Clayton, Victoria, Australia

c School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK

d Florida State University, Department of Physics, Tallahassee, FL 32306, USA

e National High Magnetic Field Laboratory, 1800 E. Paul Dirac Drive, Tallahassee, FL 32310, USA

f Department of Chemistry, University of Sheffield, Sheffield, UK

g Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, New Zealand

h School of Chemistry, Bio21 Molecular Science and Biotechnology Institute, 30 Flemington Road, The University of Melbourne, Parkville, Victoria 3010, Australia

Abstract

A unique self-assembled mixed-valence FeII–FeIII tetranuclear star has been comprehensively characterised showing a large magnetic anisotropy at the peripheral FeII centres, ferromagnetic coupling between the iron centres and field-induced SMM behaviour.

Graphical abstract: Self-assembly of a mixed-valence FeII–FeIII tetranuclear star

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Article information

DOI
https://doi.org/10.1039/C8DT01241E
Article type
Communication
Submitted
30 Mar 2018
Accepted
27 Apr 2018
First published
30 Apr 2018

Dalton Trans., 2018,47, 7118-7122

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Self-assembly of a mixed-valence FeII–FeIII tetranuclear star

D. Sertphon, P. Harding, K. S. Murray, B. Moubaraki, N. F. Chilton, S. Hill, J. Marbey, H. Adams, C. G. Davies, G. N. L. Jameson and D. J. Harding, Dalton Trans., 2018, 47, 7118 DOI: 10.1039/C8DT01241E

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