Issue 64, 2018

Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

Abstract

A blue light-promoted cross-coupling of two distinct diazo compounds was described. The reaction produces E-configured trisubstituted alkenes in good yields in the absence of catalysts and additives. The reactive free carbene intermediates were generated via selective photolysis of one of the two diazo compounds upon blue light irradiation.

Graphical abstract: Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

Supplementary files

Article information

Article type
Communication
Submitted
09 Jun 2018
Accepted
13 Jul 2018
First published
17 Jul 2018

Chem. Commun., 2018,54, 8865-8868

Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

T. Xiao, M. Mei, Y. He and L. Zhou, Chem. Commun., 2018, 54, 8865 DOI: 10.1039/C8CC04609C

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