Issue 36, 2017
From the journal:

Dalton Transactions

Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal–organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles†‡

Clément Falaise,a   Christophe Volkringer, ORCID logo *ab   Raynald Giovine,a   Bénédicte Prelot, ORCID logo c   Marielle Huvea  and  Thierry Loiseaua  

* Corresponding authors

a Unité de Catalyse et Chimie du Solide (UCCS) – UMR CNRS 8181, Université de Lille, ENSCL, Bat C7, 59652 Villeneuve d'Ascq, BP 90108, France
E-mail: christophe.volkringer@ensc-lille.fr

b Institut Universitaire de France, 1 rue Descartes, 75231 Paris Cedex 05, France

c Institut Charles Gerhardt Montpellier UMR 5253 CNRS-UM-ENSCM Université de Montpellier, Place E. Bataillon, Bât 15, cc 1502 34095 Montpellier cedex 5, France

Abstract

Aluminium-based metal–organic framework MIL-100 was utilized for the capture of actinide ([UO2]2+, Th4+) and lanthanide (Nd3+) cations. The results indicate a very quick sorption process, leading to very high cation uptakes together with selectivity for Th4+.

Graphical abstract: Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal–organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles

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Article information

DOI
https://doi.org/10.1039/C7DT02155K
Article type
Communication
Submitted
13 Jun 2017
Accepted
09 Aug 2017
First published
09 Aug 2017

Dalton Trans., 2017,46, 12010-12014

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Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal–organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles

C. Falaise, C. Volkringer, R. Giovine, B. Prelot, M. Huve and T. Loiseau, Dalton Trans., 2017, 46, 12010 DOI: 10.1039/C7DT02155K

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