In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties

Zixi Kang; Lili Fan; Sasa Wang; Daofeng Sun; Ming Xue; Shilun Qiu

doi:10.1039/C7CE00102A

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In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties†

Zixi Kang,^a Lili Fan,*^a Sasa Wang,^a Daofeng Sun,

^a Ming Xue*^b and Shilun Qiu

Author affiliations

* Corresponding authors

^a College of Science, China University of Petroleum (East China), Qingdao, Shandong, People's Republic of China
E-mail: lilifan@upc.edu.cn

^b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, P. R. China
E-mail: xueming@jlu.edu.cn

Abstract

A stable MOF membrane with guest molecules encapsulated in the pores by in situ synthesis has been successfully fabricated. The in situ confinement of linkers in the channels of the MOF membrane improves its gas separation properties, which may provide a general method for fine-tuning the pore size of MOF membranes and develop the functional applications of porous MOF materials.

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Article information

DOI: https://doi.org/10.1039/C7CE00102A
Article type: Paper
Submitted: 14 Jan 2017
Accepted: 08 Feb 2017
First published: 09 Feb 2017

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CrystEngComm, 2017,19, 1601-1606

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In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties

Z. Kang, L. Fan, S. Wang, D. Sun, M. Xue and S. Qiu, CrystEngComm, 2017, 19, 1601 DOI: 10.1039/C7CE00102A

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CrystEngComm

In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties†

Abstract

Supplementary files

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In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties

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