Issue 82, 2017
From the journal:

Chemical Communications

Assembly of the active center of organophosphorus hydrolase in metal–organic frameworks via rational combination of functional ligands†

Mengfan Xia,‡a   Caixia Zhuo,‡a   Xuejuan Ma,a   Xiaohong Zhang,a   Huaming Sun,b   Quanguo Zhai ORCID logo *b  and  Yaodong Zhang ORCID logo *a  

* Corresponding authors

a Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Changan West Road 620, Xi'an, China
E-mail: ydzhang@snnu.edu.cn
Fax: +86-29-81530727
Tel: +86-29-81530726

b Key Laboratory of Macromolecular Science of Shaanxi Province, Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, China
E-mail: zhaiqg@snnu.edu.cn

Abstract

Different from popular mimics of bimetallic nuclear centers bridged by a hydroxide, a total coordination sphere of the active center of organophosphorus hydrolase was assembled in metal–organic frameworks by rational design and combination of ligands, which resulted in efficient destruction of nerve agent stimulants without a base as a co-catalyst.

Graphical abstract: Assembly of the active center of organophosphorus hydrolase in metal–organic frameworks via rational combination of functional ligands

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Article information

DOI
https://doi.org/10.1039/C7CC06270B
Article type
Communication
Submitted
10 Aug 2017
Accepted
18 Sep 2017
First published
18 Sep 2017

Chem. Commun., 2017,53, 11302-11305

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Assembly of the active center of organophosphorus hydrolase in metal–organic frameworks via rational combination of functional ligands

M. Xia, C. Zhuo, X. Ma, X. Zhang, H. Sun, Q. Zhai and Y. Zhang, Chem. Commun., 2017, 53, 11302 DOI: 10.1039/C7CC06270B

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