A heterotopic naphthalimide ligand N-(4-picolyl)-4-(4′-carboxyphenoxy)-1,8-naphthalimide HL is utilised for the formation of self-assembled soft materials. In the presence of K+ ions, L− forms a robust photoluminescent hydrogel 1 which is reversible under thermal, mechanical or chemical stimuli.
C. S. Hawes, A. D. Lynes, K. Byrne, W. Schmitt, G. Ryan, M. E. Möbius and T. Gunnlaugsson, Chem. Commun., 2017, 53, 5989 DOI: 10.1039/C7CC03482B
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