We present a new family of supramolecular metallogels undergoing reversible multiphase transition triggered by temperature from amphiphilic alkynylplatinum(II) complexes. Further investigation revealed that intermolecular Pt⋯Pt and π–π stacking interactions facilitate such phase transitions upon increasing the temperature.
B. Jiang, L. Chen, G. Yin, Y. Wang, W. Zheng, L. Xu and H. Yang, Chem. Commun., 2017, 53, 172 DOI: 10.1039/C6CC08382J
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