Issue 15, 2016
From the journal:

RSC Advances

Synthesis of novel fluorescent 12a-aryl substituted indoxylisoquinolines via aryne-induced domino process†

A. V. Varlamov,a   N. I. Guranova,a   R. A. Novikov,b   V. V. Ilyushenkova,a   V. N. Khrustalev,a   N. S. Baleeva,c   T. N. Borisovaa  and  L. G. Voskressensky*a  

* Corresponding authors

a Organic Chemistry Department, Peoples' Friendship University of Russia, 6, Miklukho-Maklaya St., Moscow 117198, Russia
E-mail: lvoskressensky@sci.pfu.edu.ru

b N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47, Leninskij avenue, Moscow 119991, Russia

c Institute of Bioorganic Chemistry, Russian Academy of Sciences, 16/10, Miklukho-Maklaya St, Moscow 117997, Russia

Abstract

A novel effective protocol towards indolo[2,1-a]isoquinolinones via aryne-induced migration of aryl-anion in aryloxy substituted 3,4-dihydroisoquinolines is reported. These novel 12a-aryl substituted indoxylisoquinolines exhibit fluorescence properties and are characterized by green-shifted spectra and moderate quantum yields.

Graphical abstract: Synthesis of novel fluorescent 12a-aryl substituted indoxylisoquinolines via aryne-induced domino process

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Article information

DOI
https://doi.org/10.1039/C5RA25323C
Article type
Communication
Submitted
05 Dec 2015
Accepted
20 Jan 2016
First published
22 Jan 2016

RSC Adv., 2016,6, 12642-12646

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Synthesis of novel fluorescent 12a-aryl substituted indoxylisoquinolines via aryne-induced domino process

A. V. Varlamov, N. I. Guranova, R. A. Novikov, V. V. Ilyushenkova, V. N. Khrustalev, N. S. Baleeva, T. N. Borisova and L. G. Voskressensky, RSC Adv., 2016, 6, 12642 DOI: 10.1039/C5RA25323C

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