A series of lipidated macrocycles M1–M4 based on serine and threonine was designed and synthesized. Interestingly, threonine containing macrocycles assemble to vesicles, while serine-based macrocycles prefer to form fibrillar assemblies. Serine macrocycles with a 1,3-benzene dicarbonyl spacer forms fibrils while those with a biphenyl spacer resulted in a morphological change to vesicles.
M. B. Bijesh, R. Mishra, N. D. Kurur and V. Haridas, RSC Adv., 2016, 6, 41761 DOI: 10.1039/C6RA05218E
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