Issue 53, 2016, Issue in Progress

Molecular and microstructural characterization of lecithin-based oleogels made with vegetable oil

Abstract

The molecular and microstructural organization of lecithin/canola oil oleogels as a function of water content, lecithin concentration and temperature were explored using rheology, polarized light microscopy, confocal microscopy and X-ray diffraction. Using a partial phase diagram, a large gel region consisting of 10–30 wt% of lecithin was formed. The range of wo values (molar ratio of [H2O]/[lecithin]) leading to gel formation at high lecithin concentration (30 wt%) was broader (wo = 0.28–2.78) than at low concentration (10 wt%) (wo = 1.25–1.67). Rheology results showed that the gels (wo = 1.40) transitioned to liquids at 50–55 °C regardless of lecithin concentration (10, 20 and 30 wt%). Small-angle X-ray diffraction at 25 °C revealed a reverse hexagonal (HII) lattice structure with a d-spacing of 52 Å and liquid crystallites ∼1200 Å in length that rearranged with temperature evolving towards a less-ordered isotropic fluid unable to gel. At the microscale, gels showed a 3D network composed of microfibres with an average diameter of ∼1 μm. The proposed self-assembly mechanism is based on the packing of reverse hexagonal tubules parallel to the axis of fibres. The gel network forms due to branching and overlapping of these bundles at junction zones along the reverse micellar chains. In conclusion, lecithin and water content underpinned the structure and morphology of these oleogels.

Graphical abstract: Molecular and microstructural characterization of lecithin-based oleogels made with vegetable oil

Article information

Article type
Paper
Submitted
17 Feb 2016
Accepted
06 May 2016
First published
09 May 2016

RSC Adv., 2016,6, 47373-47381

Molecular and microstructural characterization of lecithin-based oleogels made with vegetable oil

M. Bodennec, Q. Guo and D. Rousseau, RSC Adv., 2016, 6, 47373 DOI: 10.1039/C6RA04324K

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