The selective synthesis of both enantiomers of a sulfur rich electron acceptor containing two 1-phenylethyl groups of the same chirality and a chiral axis is described. Cyclisation into enantiopure dithiine has been induced by the presence of a chiral substituent on the nitrogen atom of a thiazoline-2-thione dithiolate precursor.
Y. Le Gal, D. Ameline, A. Vacher, T. Roisnel, V. Dorcet and D. Lorcy, New J. Chem., 2016, 40, 9930 DOI: 10.1039/C6NJ02292H
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