A robust and recyclable polyurea-encapsulated copper(i) chloride for one-pot ring-opening/Huisgen cycloaddition/CO2 capture in water

Abstract

Multicomponent ring-opening/Huisgen cycloaddition reactions combined with CO₂ capture with a polyurea-encapsulated copper salt as a catalyst that in situ formed from simple CuCl and soluble polyurea during the reaction were carried out successfully for the synthesis of β-hydroxytriazoles under exceptionally mild conditions, in which the polyurea-encapsulated copper(I) chloride proved to be a robust and recyclable catalyst system with high yields as well as excellent chemoselectivity in this reaction.