Issue 11, 2016
From the journal:

Dalton Transactions

Ionic self-assembly affords mesoporous ionic networks by crosslinking linear polyviologens with polyoxometalate clusters†

Guojian Chen,ab   Wei Hou,a   Jing Li,a   Xiaochen Wang,a   Yu Zhou*a  and  Jun Wang*a  

* Corresponding authors

a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, China
E-mail: njutzhouyu@njtech.edu.cn, junwang@njtech.edu.cn
Tel: +(86) 25-83172264

b School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou, China

Abstract

Ionic-bonded mesoporous ionic networks were prepared by the ionic self-assembly of polyoxometalate (POM) clusters with linear cationic polyviologens in water. The POM-enriched PMIN-2(V) possesses a high surface area up to 120 m2 gāˆ’1, exhibiting superior non-noble metal heterogeneous catalytic performance in the ambient aerobic selective oxidation of 5-hydroxymethylfurfural.

Graphical abstract: Ionic self-assembly affords mesoporous ionic networks by crosslinking linear polyviologens with polyoxometalate clusters

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Article information

DOI
https://doi.org/10.1039/C6DT00070C
Article type
Communication
Submitted
07 Jan 2016
Accepted
15 Feb 2016
First published
16 Feb 2016

Dalton Trans., 2016,45, 4504-4508

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Ionic self-assembly affords mesoporous ionic networks by crosslinking linear polyviologens with polyoxometalate clusters

G. Chen, W. Hou, J. Li, X. Wang, Y. Zhou and J. Wang, Dalton Trans., 2016, 45, 4504 DOI: 10.1039/C6DT00070C

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