NiCo2S4 nanoparticles//activated balsam pear pulp for asymmetric hybrid capacitors
Abstract
Cauliflower-like NiCo2S4 nanoparticles (NPs) for use as battery-type materials have been synthesized via a simple one-step route solvothermal method with thioacetamide (TAA) as the sulfur source. The synthesis of the Ni–Co precursors and the S2− anion exchange reactions occur at the same time, which is time-effective and cost-effective compared to other methods. The obtained NiCo2S4 NPs display very competitive electrochemical performance (a specific capacitance of 2480 F g−1 is achieved at a current density of 0.5 A g−1, excellent rate capability with 68% of the original capacitance remained at 10 A g−1 and ideal cycle stability with 80% capacitance remained after 3000 cycles) with high mass-loading (5 mg cm−2). In addition, low-cost activated balsam pear pulp (ABPP) is developed as a capacitor-type carbon material for supercapacitors with ideal electrochemical performances. The asymmetric hybrid capacitors (AHCs) are further assembled into pouch cells using battery-type NiCo2S4 NPs as the positive electrode, capacitor-type ABPP as the negative electrode and flexible carbon papers as the current collector. The AHCs demonstrate high power density (3.52 kW kg−1 at an energy density of 3.72 Wh kg−1) and cycle stability (72.4% after 9000 cycles).