The direct redox reaction (galvanic displacement) between Pd2+ and substrate Si was used to deposit Pd on Si, and the Pd–Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.
Q. Wei, Y. Shi, K. Sun and B. Xu, Chem. Commun., 2016, 52, 3026 DOI: 10.1039/C5CC07474F
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