Issue 10, 2015

‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

Abstract

A new family of isomorphous [Cu4Ln] clusters (LnIII = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in CuII/LnIII chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.

Graphical abstract: ‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

Supplementary files

Article information

Article type
Research Article
Submitted
12 Aug 2015
Accepted
08 Sep 2015
First published
09 Sep 2015

Inorg. Chem. Front., 2015,2, 945-948

Author version available

‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang and T. C. Stamatatos, Inorg. Chem. Front., 2015, 2, 945 DOI: 10.1039/C5QI00146C

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