Issue 56, 2015
From the journal:

RSC Advances

Size-selective incorporation of donor–acceptor linked dyad cations into zeolite Y and long-lived charge separation†

Shunichi Fukuzumi,*abc   Akinori Itoh,a   Kei Ohkuboac  and  Tomoyoshi Suenobua  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, ALCA and SENTAN, Japan Science and Technology Agency (JST), Osaka University, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7370

b Faculty of Science and Engineering, ALCA and SENTAN, Japan Science and Technology Agency (JST), Meijo University, Nagoya, Aichi 468-0073, Japan

c Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea

Abstract

Cationic electron donor–acceptor dyads are incorporated into a supercage of zeolite Y by cation exchange depending on the size of the dyad cations. 3-Mesityl-1-methylquinolinium ion was small enough to be incorporated into the zeolite supercage, exhibiting long-lived charge separation upon photoexcitation.

Graphical abstract: Size-selective incorporation of donor–acceptor linked dyad cations into zeolite Y and long-lived charge separation

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Article information

DOI
https://doi.org/10.1039/C5RA06165B
Article type
Communication
Submitted
07 Apr 2015
Accepted
08 May 2015
First published
08 May 2015

RSC Adv., 2015,5, 45582-45585

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Size-selective incorporation of donor–acceptor linked dyad cations into zeolite Y and long-lived charge separation

S. Fukuzumi, A. Itoh, K. Ohkubo and T. Suenobu, RSC Adv., 2015, 5, 45582 DOI: 10.1039/C5RA06165B

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