A cost effective approach for developing substrate stable TiO2 nanotube arrays with tuned morphology: a comprehensive study on the role of H2O2 and anodization potential
Abstract
A rapid growth rate of vertically grown and ‘substrate-stable’ titania (TiO2) nanotubes with self-organized nanotubular structures is realized in an electrolyte consisting of ethylene glycol (EG) and ammonium fluoride (NH4F) at various concentrations of hydrogen peroxide (H2O2). We have explored the possible growth of ordered TiO2 nanotubes in the electrolyte with four different concentrations of H2O2 (3, 5, 10 and 15 vol%) at six different applied potentials (30, 40, 50, 60, 70 and 80 V), where self-organized TiO2 nanotube arrays with the maximum tube length of 28 μm have been attained within 3 h of anodization in the electrolyte containing 10 vol% H2O2 at 60 V. The porosity of the synthesized nanotube samples is found to vary with the concentration of H2O2 and the applied potential. The samples were characterized by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD).