Hydrothermal synthesis and magnetic behaviour of beta-Li3VF6 and Na3VF6

Lei Ge; Long Yuan; Keke Huang; Wenchun Feng; Hairui Fang; Shouhua Feng

doi:10.1039/C5NJ00284B

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Hydrothermal synthesis and magnetic behaviour of beta-Li₃VF₆ and Na₃VF₆

Lei Ge,^a Long Yuan,^a Keke Huang,^a Wenchun Feng,

^b Hairui Fang^a and Shouhua Feng*^a

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* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: shfeng@mail.jlu.edu.cn
Fax: +86-431-85168624
Tel: +86-431-85168661

^b Department of Chemical Engineering, University of Michigan, Ann Arbor 48109, USA

Abstract

Fluorides and oxide-fluorides play important roles in several technological fields. Herein, we have synthesized the crystals of β-Li₃VF₆ and Na₃VF₆ under mild hydrothermal conditions without any hydrofluoric acid. These two compounds were well-crystallized and showed antiferromagnetic interactions with isolated magnetic units.

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DOI: https://doi.org/10.1039/C5NJ00284B
Article type: Letter
Submitted: 02 Feb 2015
Accepted: 24 Mar 2015
First published: 25 Mar 2015

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New J. Chem., 2015,39, 5080-5083

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Hydrothermal synthesis and magnetic behaviour of beta-Li₃VF₆ and Na₃VF₆

L. Ge, L. Yuan, K. Huang, W. Feng, H. Fang and S. Feng, New J. Chem., 2015, 39, 5080 DOI: 10.1039/C5NJ00284B

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New Journal of Chemistry

Hydrothermal synthesis and magnetic behaviour of beta-Li₃VF₆ and Na₃VF₆

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Hydrothermal synthesis and magnetic behaviour of beta-Li₃VF₆ and Na₃VF₆

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