Issue 2, 2015
From the journal:

New Journal of Chemistry

Selective recognition of biogenic amine hydrochlorides by heteroditopic dihomooxacalix[4]arenes†

Giuseppe Gattuso,a   Anna Notti,a   Melchiorre F. Parisi,*a   Ilenia Pisagatti,a   Paula Maria Marcos,*bc   José Rosário Ascenso,d   Giovanna Brancatellie  and  Silvano Geremiae  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy
E-mail: mparisi@unime.it
Fax: +39 090 393895
Tel: +39 090 6765170

b Centro de Ciências Moleculares e Materiais, Faculdade de Ciências da Universidade de Lisboa, Edifício C8, 1749-016 Lisboa, Portugal

c Faculdade de Farmácia da Universidade de Lisboa, Av. Prof. Gama Pinto, 1649-003 Lisboa, Portugal
E-mail: pmmarcos@fc.ul.pt
Fax: +351 21 7500979

d Centro de Química Estrutural, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

e Centro di Eccellenza in Biocristallografia, Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via L. Giorgieri 1, 34127 Trieste, Italy

Abstract

Ion-pair recognition–complexation of monoamine neurotransmitters and trace amine hydrochlorides takes place – with outstanding efficiency and selectivity – within the π-rich cavity and the pocket formed at the lower rim by the two ureido moieties of the tailor-made dihomooxacalixarene receptors 1 and 2. The solid-state structure of 1 is also reported.

Graphical abstract: Selective recognition of biogenic amine hydrochlorides by heteroditopic dihomooxacalix[4]arenes

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Article information

DOI
https://doi.org/10.1039/C4NJ01423E
Article type
Letter
Submitted
23 Aug 2014
Accepted
08 Dec 2014
First published
08 Dec 2014

New J. Chem., 2015,39, 817-821

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Selective recognition of biogenic amine hydrochlorides by heteroditopic dihomooxacalix[4]arenes

G. Gattuso, A. Notti, M. F. Parisi, I. Pisagatti, P. M. Marcos, J. R. Ascenso, G. Brancatelli and S. Geremia, New J. Chem., 2015, 39, 817 DOI: 10.1039/C4NJ01423E

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