Issue 37, 2015
From the journal:

Dalton Transactions

α-Diimine nickel complexes of ethylene and related alkenes†

Yanxia Zhao,a   Zeyi Wang,ab   Xiaojing Jing,a   Qingsong Dong,c   Shida Gong,d   Qian-Shu Li,d   Juan Zhang,b   Biao Wua  and  Xiao-Juan Yang*a  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China
E-mail: yangxiaojuan@nwu.edu.cn

b Institute of Chemistry in Shaanxi Province, School of Chemical Engineering, Northwest University, Xi'an 710069, China

c State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China

d Center for Computational Quantum Chemistry, South China Normal University, Guangzhou 510631, China

Abstract

A series of nickel mono(alkene) complexes, [LNi(alkene)], which consist of nickel(0) and neutral α-diimine ligand L (L = [(2,6-iPr2C6H3)NC(Me)]2), have been synthesized. The bonding and structures of the complexes were studied by X-ray diffraction, spectroscopic methods, and DFT computations.

Graphical abstract: α-Diimine nickel complexes of ethylene and related alkenes

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Article information

DOI
https://doi.org/10.1039/C5DT02333E
Article type
Communication
Submitted
19 Jun 2015
Accepted
17 Aug 2015
First published
26 Aug 2015

Dalton Trans., 2015,44, 16228-16232

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α-Diimine nickel complexes of ethylene and related alkenes

Y. Zhao, Z. Wang, X. Jing, Q. Dong, S. Gong, Q. Li, J. Zhang, B. Wu and X. Yang, Dalton Trans., 2015, 44, 16228 DOI: 10.1039/C5DT02333E

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