First copper(II) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

Pablo Fuentealba; Catalina Cortés; Nathalie Audebrand; Eric Le Fur; Verónica Paredes-García; Diego Venegas-Yazigi; Jorge Manzur; Evgenia Spodine

doi:10.1039/C5DT01540E

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First copper(ii) phase M ^′_0.2Mn_0.8PS₃·0.25H₂O and analogous M′ = Co^II, Ni^II and Zn^II materials obtained by microwave assisted synthesis†

Pablo Fuentealba,^ab Catalina Cortés,^ab Nathalie Audebrand,^c Eric Le Fur,^d Verónica Paredes-García,^be Diego Venegas-Yazigi,^bf Jorge Manzur*^bg and Evgenia Spodine*^ab

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* Corresponding authors

^a Facultad de Ciencias Químicas y Farmacéuticas, U. de Chile, Santiago, Chile
E-mail: espodine@uchile.cl

^b CEDENNA, Santiago, Chile

^c Université de Rennes 1, Institut des Sciences Chimiques de Rennes-UMR 6226, Rennes, France

^d Ecole Nationale Supérieure de Chimie, Institut des Sciences Chimiques de Rennes-UMR 6226, Rennes, France

^e Departamento de Ciencias Químicas, Universidad Andres Bello, Santiago, Chile

^f Facultad de Química y Biología, U. de Santiago de Chile, Santiago, Chile

^g Facultad de Ciencias Físicas y Matemáticas, U. de Chile, Santiago, Chile

Abstract

M^′_0.2Mn_0.8PS₃·0.25H₂O materials are obtained by a mild microwave assisted reaction (M′ = Co^II, Ni^II, Cu^II, Zn^II), which permitted us to obtain the first copper(II) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS₃.

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Article information

DOI: https://doi.org/10.1039/C5DT01540E
Article type: Communication
Submitted: 23 Apr 2015
Accepted: 04 Jun 2015
First published: 04 Jun 2015

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Dalton Trans., 2015,44, 12493-12496

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First copper(II) phase M^′_0.2Mn_0.8PS₃·0.25H₂O and analogous M′ = Co^II, Ni^II and Zn^II materials obtained by microwave assisted synthesis

P. Fuentealba, C. Cortés, N. Audebrand, E. Le Fur, V. Paredes-García, D. Venegas-Yazigi, J. Manzur and E. Spodine, Dalton Trans., 2015, 44, 12493 DOI: 10.1039/C5DT01540E

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Dalton Transactions