Issue 86, 2015
From the journal:

Chemical Communications

Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides†

Charlotte D. Vacognea  and  Helmut Schlaad*b  

* Corresponding authors

a Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, 14424 Potsdam, Germany

b University of Potsdam, Institute of Chemistry, Karl-Liebknecht-Straße 24-25, 14476 Potsdam, Germany
E-mail: schlaad@uni-potsdam.de

Abstract

Stable commercial primary ammonium chlorides were combined with tertiary amines to initiate the controlled ring opening polymerisation of amino acid N-carboxyanhydrides to yield polypeptides with defined end group structure, predetermined molar mass and narrow molar mass distribution.

Graphical abstract: Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides

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Article information

DOI
https://doi.org/10.1039/C5CC06905J
Article type
Communication
Submitted
17 Aug 2015
Accepted
07 Sep 2015
First published
07 Sep 2015

Chem. Commun., 2015,51, 15645-15648

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Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides

C. D. Vacogne and H. Schlaad, Chem. Commun., 2015, 51, 15645 DOI: 10.1039/C5CC06905J

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