The photo-induced electron transfers in the “straight up” ionic assemblies [Pd32+]⋯MCP and [Pd32+]⋯DCP⋯[Pd32+] ([Pd32+]* → MCP or DCP) are ultrafast (<85 fs) indicating that it is not necessary to have a strong coordination bond or a bent geometry to obtain fast electron injection in porphyrin-containing DSSCs.
P. Luo, P. Karsenti, G. Brisard, B. Marsan and P. D. Harvey, Chem. Commun., 2015, 51, 17305 DOI: 10.1039/C5CC06779K
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