An unprecedented layered Pb-Kemp's triacid compound, Pb3[C6(CH3)3(CO2)3H6]2[DMF]3, has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb2+ and Cd2+ with Kemp's triacid reveals higher selectivity of Cd2+ over Pb2+.
![Graphical abstract: Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C5CC05360A&imageInfo.ImageIdentifier.Year=2015)
S. B. Kim, D. W. Lee, S. Chang and K. M. Ok, Chem. Commun., 2015, 51, 13166 DOI: 10.1039/C5CC05360A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
