Issue 59, 2015
From the journal:

Chemical Communications

Visible light promoted hydration of alkynes catalyzed by rhodium(iii) porphyrins†

Xu Liu,a   Lianghui Liu,a   Zikuan Wanga  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn

Abstract

Visible light promoted hydration of a wide scope of alkynes to ketones catalyzed by rhodium(III) porphyrin complexes was described. The key intermediate β-carbonyl alkyl was observed and independently synthesized. The rate of photolysis is over two orders of magnitude faster than that of the thermal process.

Graphical abstract: Visible light promoted hydration of alkynes catalyzed by rhodium(iii) porphyrins

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Article information

DOI
https://doi.org/10.1039/C5CC04015A
Article type
Communication
Submitted
14 May 2015
Accepted
14 Jun 2015
First published
16 Jun 2015

Chem. Commun., 2015,51, 11896-11898

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Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins

X. Liu, L. Liu, Z. Wang and X. Fu, Chem. Commun., 2015, 51, 11896 DOI: 10.1039/C5CC04015A

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