Herein we demonstrate redox switchable emission from a sensitised, europium–ferrocene containing, molecular film assembled by a novel nitrene-based strategy. Electrochemical modulation of europium emission upon switching the ferrocene moiety's redox state is ascribed to the reversible generation of a quenching ferrocenium species.
J. Lehr, M. Tropiano, P. D. Beer, S. Faulkner and J. J. Davis, Chem. Commun., 2015, 51, 6515 DOI: 10.1039/C5CC01097G
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