A zinc borate Zn(1,3-DAP)[B4O7] (1) was prepared. 1 was revealed to be a rare chiral zeolitic framework based on a [B4O9] cluster. The combination of a [B4O9] cluster and Zn(1,3-DAP)O3 chain produced a helical ribbon motif and gave rise to a single-stranded helical channel.
![Graphical abstract: Zn(1,3-DAP)[B4O7]: a rare chiral zeolitic framework constructed of four-connected [B4O9] clusters with a single-stranded helical channel](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC08202H&imageInfo.ImageIdentifier.Year=2015)
C. Pan, L. Zhong, F. Zhao, H. Yang and J. Zhou, Chem. Commun., 2015, 51, 753 DOI: 10.1039/C4CC08202H
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