Issue 51, 2014
From the journal:

RSC Advances

Novel transmetalation reaction for electrolyte synthesis for rechargeable magnesium batteries†

Zhirong Zhao-Karger,*a   Jonathan E. Mueller,b   Xiangyu Zhao,ac   Olaf Fuhr,ad   Timo Jacobbe  and  Maximilian Fichtnerae  

* Corresponding authors

a Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), P.O. Box 3640, D-76021 Karlsruhe, Germany
E-mail: zhirong.zhao-karger@kit.edu
Fax: +49-721-608 28298

b Institute of Electrochemistry, Ulm University, D-89069 Ulm, Germany

c College of Materials Science and Engineering, Nanjing Tech University, 210009 Nanjing, China

d Karlsruhe Nano Micro Facility (KNMF), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

e Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU), D-89081 Ulm, Germany

Abstract

A simple strategy for the synthesis of electrolyte solutions comprised of binuclear magnesium aluminate complexes without the need for organomagnesium compounds is established. The as-prepared phenolate based electrolyte exhibits an anodic stability of up to 3.4 V, good ionic conductivity and air-stability.

Graphical abstract: Novel transmetalation reaction for electrolyte synthesis for rechargeable magnesium batteries

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Article information

DOI
https://doi.org/10.1039/C4RA03867C
Article type
Communication
Submitted
28 Apr 2014
Accepted
09 Jun 2014
First published
09 Jun 2014

RSC Adv., 2014,4, 26924-26927

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Novel transmetalation reaction for electrolyte synthesis for rechargeable magnesium batteries

Z. Zhao-Karger, J. E. Mueller, X. Zhao, O. Fuhr, T. Jacob and M. Fichtner, RSC Adv., 2014, 4, 26924 DOI: 10.1039/C4RA03867C

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