A regio- and stereo-controlled, one-pot amidoglycosylation of alcohols has been achieved using O-acetylated glycals, trichloroethoxysulfonamide, and iodosobenzene in the presence of a rhodium(II) catalyst. The reaction would proceed via stereoselective intermolecular aziridination of the glycal.
T. Murakami, Y. Sato, K. Yoshioka and M. Tanaka, RSC Adv., 2014, 4, 21584 DOI: 10.1039/C4RA02367F
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