Synthesis and characterization of a new aluminophosphate with a Al3P6O249− three-dimensional framework

Ying Wang; Shilie Pan; Shujuan Han; Lingyun Dong; Min Zhang; Kui Wu

doi:10.1039/C3NJ01484C

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Synthesis and characterization of a new aluminophosphate with a Al₃P₆O₂₄⁹⁻ three-dimensional framework†

Ying Wang,^ab Shilie Pan,*^a Shujuan Han,^a Lingyun Dong,^ab Min Zhang^a and Kui Wu^a

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* Corresponding authors

^a Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40–1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn
Fax: +86-991-3838957
Tel: +86-991-3674558

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A novel mixed-alkali metal aluminophosphate, K₆Na₃Al₃P₆O₂₄, has been successfully synthesized and structurally characterized. The compound contains a unique Al₃P₆O₂₄⁹⁻ three-dimensional framework composed of AlO₄ and PO₄ tetrahedra with an Al/P ratio of 1/2. This compound melts congruently and is optically transparent from 352 to 2600 nm.

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Article information

DOI: https://doi.org/10.1039/C3NJ01484C
Article type: Letter
Submitted: 26 Nov 2013
Accepted: 04 Jan 2014
First published: 07 Jan 2014

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New J. Chem., 2014,38, 889-892

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Synthesis and characterization of a new aluminophosphate with a Al₃P₆O₂₄⁹⁻ three-dimensional framework

Y. Wang, S. Pan, S. Han, L. Dong, M. Zhang and K. Wu, New J. Chem., 2014, 38, 889 DOI: 10.1039/C3NJ01484C

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