Issue 7, 2014
From the journal:

Dalton Transactions

A facile route to Ru-alkylidenes†

Adam M. McKintya  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

Reactions of dithioacetal E(CH2CH2S)2CHR (E = O, S, R = Ph, C6F5) and O(C6H4S)2CHPh with either Ru(cod)(cot) or Ru(PPh3)3(H)2 are used to prepare the Ru-alkylidene complexes E(CH2CH2S)2RuCHPh(L), O(C6H4S)2RuCHPh(L) (L = PCy3, SIMes) in high yields.

Graphical abstract: A facile route to Ru-alkylidenes

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Article information

DOI
https://doi.org/10.1039/C3DT53525H
Article type
Communication
Submitted
16 Dec 2013
Accepted
17 Dec 2013
First published
02 Jan 2014

Dalton Trans., 2014,43, 2710-2712

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A facile route to Ru-alkylidenes

A. M. McKinty and D. W. Stephan, Dalton Trans., 2014, 43, 2710 DOI: 10.1039/C3DT53525H

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