We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.
L. Xiong, H. Zhang, A. Zhong, Z. He and K. Huang, Chem. Commun., 2014, 50, 14778 DOI: 10.1039/C4CC06573E
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