Issue 80, 2014
From the journal:

Chemical Communications

Cyclometalated gold(iii) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination†

Karen Ka-Yan Kung,a   Hok-Ming Ko,a   Jian-Fang Cui,a   Hiu-Chi Chong,a   Yun-Chung Leung*a  and  Man-Kin Wong*a  

* Corresponding authors

a State Key Laboratory of Chirosciences and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, China
E-mail: mankin.wong@polyu.edu.hk, thomas.yun-chung.leung@polyu.edu.hk
Fax: +852-2364-9932

Abstract

Modular assembly of cyclometalated gold(III) complexes by choosing appropriate bidentate C,N-donor ligands and ancillary ligands for chemoselective cysteine modification of peptides and proteins via C–S bond-forming reductive elimination has been achieved.

Graphical abstract: Cyclometalated gold(iii) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

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Article information

DOI
https://doi.org/10.1039/C4CC04467C
Article type
Communication
Submitted
12 Jun 2014
Accepted
18 Aug 2014
First published
18 Aug 2014

Chem. Commun., 2014,50, 11899-11902

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Cyclometalated gold(III) complexes for chemoselective cysteine modification via ligand controlled C–S bond-forming reductive elimination

K. K. Kung, H. Ko, J. Cui, H. Chong, Y. Leung and M. Wong, Chem. Commun., 2014, 50, 11899 DOI: 10.1039/C4CC04467C

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