Issue 44, 2014
From the journal:

Chemical Communications

Dehydrogenation of a tertiary amine-borane by a rhenium complex†

Sohail Muhammad,a   Salvador Moncho,a   Edward N. Brothersa  and  Ashfaq A. Bengali*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University at Qatar, Doha, Qatar
E-mail: ashfaq.bengali@qatar.tamu.edu

Abstract

Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

Graphical abstract: Dehydrogenation of a tertiary amine-borane by a rhenium complex

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Article information

DOI
https://doi.org/10.1039/C4CC01771D
Article type
Communication
Submitted
09 Mar 2014
Accepted
14 Apr 2014
First published
15 Apr 2014

Chem. Commun., 2014,50, 5874-5877

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Dehydrogenation of a tertiary amine-borane by a rhenium complex

S. Muhammad, S. Moncho, E. N. Brothers and A. A. Bengali, Chem. Commun., 2014, 50, 5874 DOI: 10.1039/C4CC01771D

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