Hydroxylation of alkanes by a mononuclear nonheme iron(V)–oxo complex, [Fe(V)(O)(TAML)]−, is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction–oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.
E. Kwon, K. Cho, S. Hong and W. Nam, Chem. Commun., 2014, 50, 5572 DOI: 10.1039/C4CC01058B
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