Issue 28, 2014
From the journal:

Chemical Communications

Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution†

Teresa Eaton,‡a   Jian Lin,‡ab   Justin N. Cross,ab   Jared T. Stritzingera  and  Thomas E. Albrecht-Schmitt*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, 310 DLC, Tallahassee, Florida 32306, USA
E-mail: albrecht-schmitt@chem.fsu.edu

b Department of Civil & Environmental Engineering & Earth Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, Indiana, USA

Abstract

Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (ThIVvs. LnIII; SeIVO32−vs. IVO3−) are possible in this structure type.

Graphical abstract: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

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Article information

DOI
https://doi.org/10.1039/C4CC00537F
Article type
Communication
Submitted
21 Jan 2014
Accepted
17 Feb 2014
First published
17 Feb 2014

Chem. Commun., 2014,50, 3668-3670

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Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

T. Eaton, J. Lin, J. N. Cross, J. T. Stritzinger and T. E. Albrecht-Schmitt, Chem. Commun., 2014, 50, 3668 DOI: 10.1039/C4CC00537F

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