Issue 26, 2013

A platinum turnstile with a palladium lock

Abstract

An organometallic molecular turnstile composed of a stator based on an α,ω-diphosphine bearing, in a symmetric fashion, the 2,6-pyridyl diamide moiety as a central tridentate chelating unit and a rotor composed of Pt(II) equipped with two pyridyl groups in trans configuration was designed. The switching between its open and closed states using Pd(II) was investigated both in solution and in the solid state.

Graphical abstract: A platinum turnstile with a palladium lock

Supplementary files

Article information

Article type
Paper
Submitted
26 Mar 2013
Accepted
01 May 2013
First published
02 May 2013

Dalton Trans., 2013,42, 9740-9745

A platinum turnstile with a palladium lock

N. Zigon, A. Guenet, E. Graf, N. Kyritsakas and M. W. Hosseini, Dalton Trans., 2013, 42, 9740 DOI: 10.1039/C3DT50809A

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