Issue 94, 2013
From the journal:

Chemical Communications

Repetitive stepwise rotaxane formation toward programmable molecular arrays†

Yasuyuki Yamada,ab   Masa-aki Okadaa  and  Kentaro Tanaka*ac  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan
E-mail: kentaro@chem.nagoya-u.ac.jp
Fax: +81-52-789-2940
Tel: +81-52-789-2940

b Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan

c CREST, Japan Science and Technology Agency, Honcho 4-1-8, Kawaguchi-shi, Saitama 332-0012, Japan

Abstract

We present a novel strategy to synthesize multi-molecular arrays in a programmable way by stepwise elongation based on repetition of two-fold rotaxane formation and construction of threads. A cofacially triply stacked porphyrin array was obtained via the repetitive two-fold rotaxane formation.

Graphical abstract: Repetitive stepwise rotaxane formation toward programmable molecular arrays

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Article information

DOI
https://doi.org/10.1039/C3CC46859C
Article type
Communication
Submitted
07 Sep 2013
Accepted
04 Oct 2013
First published
18 Oct 2013

Chem. Commun., 2013,49, 11053-11055

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Repetitive stepwise rotaxane formation toward programmable molecular arrays

Y. Yamada, M. Okada and K. Tanaka, Chem. Commun., 2013, 49, 11053 DOI: 10.1039/C3CC46859C

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