Issue 89, 2013
From the journal:

Chemical Communications

One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer†

Takashi Kajiwara,a   Masakazu Higuchi,b   Akihiro Yuasa,a   Hideyuki Higashimura*a  and  Susumu Kitagawa*bc  

* Corresponding authors

a Advanced Materials Research Laboratory, Sumitomo Chemical Co., Ltd., 6 Kitahara, Tsukuba, Ibaraki 300-3294, Japan
E-mail: higashimura@sc.sumitomo-chem.co.jp

b Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida Ushinomiyacho, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp

c Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinated solvent.

Graphical abstract: One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer

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Article information

DOI
https://doi.org/10.1039/C3CC43384F
Article type
Communication
Submitted
07 May 2013
Accepted
27 Jun 2013
First published
28 Jun 2013

Chem. Commun., 2013,49, 10459-10461

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One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer

T. Kajiwara, M. Higuchi, A. Yuasa, H. Higashimura and S. Kitagawa, Chem. Commun., 2013, 49, 10459 DOI: 10.1039/C3CC43384F

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