Issue 5, 2013
From the journal:

Chemical Communications

Lewis base mediated efficient synthesis and solvation-like host–guest chemistry of covalent organic framework-1†

Suresh Babu Kalidindi,a   Christian Wiktor,ab   Ayyappan Ramakrishnan,c   Jana Weßing,a   Andreas Schneemann,a   Gustaaf Van Tendeloob  and  Roland A. Fischer*a  

* Corresponding authors

a Inorganic Chemistry II-Organometallics & Materials Faculty of Chemistry and Biochemistry, Ruhr University Bochum, 44780 Bochum, Germany
E-mail: roland.fischer@rub.de

b EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium

c Faculty of Chemistry and Biochemistry, Ruhr University Bochum, 44780 Bochum, Germany

Abstract

N-Lewis base mediated room temperature synthesis of covalent organic frameworks (COFs) starting from a solution of building blocks instead of partially soluble building blocks was developed. This protocol shifts COF synthetic chemistry from sealed tubes to open beakers. Non-conventional inclusion compounds of COF-1 were obtained by vapor phase infiltration of ferrocene and azobenzene, and solvation like effects were established.

Graphical abstract: Lewis base mediated efficient synthesis and solvation-like host–guest chemistry of covalent organic framework-1

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Article information

DOI
https://doi.org/10.1039/C2CC37183A
Article type
Communication
Submitted
02 Oct 2012
Accepted
05 Nov 2012
First published
06 Nov 2012

Chem. Commun., 2013,49, 463-465

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Lewis base mediated efficient synthesis and solvation-like host–guest chemistry of covalent organic framework-1

S. B. Kalidindi, C. Wiktor, A. Ramakrishnan, J. Weßing, A. Schneemann, G. Van Tendeloo and R. A. Fischer, Chem. Commun., 2013, 49, 463 DOI: 10.1039/C2CC37183A

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