Issue 3, 2013
From the journal:

Chemical Science

Stereoselective intramolecular cyclopropanation through catalytic olefin activation†

Xueliang Huang,a   Sebastian Klimczyk,a   Luís F. Veirosb  and  Nuno Maulide*a  

* Corresponding authors

a Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 145470, Mülheim an der Ruhr, Germany
E-mail: maulide@mpi-muelheim.mpg.de
Fax: +49-208-3062999
Tel: +49-206-3062450

b Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal

Abstract

A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.

Graphical abstract: Stereoselective intramolecular cyclopropanation through catalytic olefin activation

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Article information

DOI
https://doi.org/10.1039/C2SC21914J
Article type
Edge Article
Submitted
05 Nov 2012
Accepted
03 Dec 2012
First published
04 Jan 2013

Chem. Sci., 2013,4, 1105-1110

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Stereoselective intramolecular cyclopropanation through catalytic olefin activation

X. Huang, S. Klimczyk, L. F. Veiros and N. Maulide, Chem. Sci., 2013, 4, 1105 DOI: 10.1039/C2SC21914J

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